These medicinal plants are extensively used as traditional medicine for treatment of various ailments by local physicians in the area from where these plants wer… Rest of these, all the other metals exceeded the limit. &��$>�?������ĿsNPy�P��|Y?��;ٓ�o�_�7_��/��rXȍL]�"��R���OrU��e83w� ��0��eB�π��y*#�٢sAP鮛��;D���-a]l�c�5q��bU�kO��Е��G��ȳ�8��%�3{g8�O� ��p�]V�#�.��d�ˌ[H�H`j��p7���\�2��{��`�5U*�x^f�������otmġ����t/cW�`%��å�s�b�E:�>tR�Eg��!�|� �p�i`��N�^i��80�qW�lJ�|�Ln�����|(�@�P׌��L�(�ĭ��ӗ�|���Ts�Z�y�q�Je�8�po[���,�j)�?j� �����]��nнW��� �����\�F�:o�. Introduction In an aquatic ecosystem, soil is one of the most important part and ecological factor. In soil sample 11 and soil sample 12 concentration of nickel was recorded above … ��4kj��7�s��/��څ� ��_ۧ��m ;b�Wi������� ��0�nc����a�;h���t�n;��v`�a�1:v��8��6 �ڏ���؏�)VR'�[����x�Һuać2+U])⎼�^�;-�y�e�iU�~�1���(���c���å�kС'ѵ�m@4Ⱦ9���u�$ps^Vcyk���e�I�I��~�(fA�tx|�?��7P-��6�����^;�}ȩ_+m2C����F���:� m�g��T��1��i��˩M[�v#�=D�r|L�Y��~�����d��5|�m��6�~��܉m������ ]�N���I롾(��GW�@��i$ fe���.M#1�_*I�GӘ�@��Y���K2�E��{�9A�@�����l]��?��F�Ѡ The concentration of heavy metals including As, Cd, Cr, Cu, Hg, Pb, Zn, Sb, Co and Ni in soil of the EU was assessed. [Zigham Hassan et which is below the permissible limit. Soil … Some parameters were above permissible limit and some below permissible limit which affect the quality and productivity of pond soil. %���� Nickel toxicity levels vary widely between 25 to 50 ppm (Mishra and Kar, 1974). Nickel concentrations in groundwater depend on the soil use, pH, and depth of sampling. %PDF-1.2 As far as I know MoEF or CPCB has not given any permissible limits of heavy metal in soil unlike other countries like EU, USA etc. Soil samples were also collected from the site at 4 m depth for determining soil moisture content, bulk density, particle size distribution, atterberg limits, optimum moisture content and permeability (falling head). The effect of soil pH value on concentrations of Ni, Cu and Zn in ryegrass grown on two sludge-treated soils was examined under field conditions and the maximum permissible soil limit values for these elements were determined which prevent phytotoxicity in crops where sewage sludge is applied to agricultural soils with pH <6.0. Keywords: Soil quality, chemical parameters, Nagchoon pond, Khandwa. In the collected soil samples concentration concentration of nickel was recorded with in the permissible limit set by WHO. Optimum limit of each element is beneficial for plant growth as well as soil fertility. Nickel and copper concentrations are above acceptable limit and other metal concentration is within the acceptable limit. The average concentration of nickel was however, in the range of what was measured from studies in Abia (Okoronkwo et al., 2006) and Lagos state (Oyelola and Babatunde, 2008). Heavy metals (Cd, Zn, Cu, Cr, Pb and Ni) in the control samples were found to be 0.35, 40.00, 88.55, 0.65, 238 and 0.65 mg/kg for Cadmium, Zinc, Copper, Chromium, Lead and Nickel in plants respectively. In the collected soil samples concentration of nickel ranged between 0.150 to 1.031mg/kg. In all the collected plant samples, the concentration of arsenic was recorded in the range from 0.0107 to 0.2495 mg kg -1. Krishi Vishwa Vidyalaya, Jabalpur 482 004, M.P., India Key words : Nickel, Toxicity, Uptake, Availability, and Reactions in Soil, Ni hyper accumulation. %���� Department of Soil Science and Agricultural Chemistry J.N. Field experiments in calcareous and acidic field soils were conducted to study the effects of copper (Cu) and nickel (Ni) added to soils on maize growth and metal accumulation in maize plants. stream 4 0 obj endobj Nickel (Ni) Residential Allotment Commercial Agricultural and after sewage sludge application ... environment and in particular of the soil when sludge is applied to agricultural land. Acid rain increases the mobility of nickel in the soil and thus might increase nickel concentrations in groundwater (IPCS, 1991). • A need for a comprehensive monitoring of HM in soil in the European Union is proposed. The soil samples were between 0.066, 9.50, 4.83, 55.63, The average concentration in groundwater in the Netherlands ranges from 7.9 µg/L (urban areas) to 16.6 µg/L (rural areas). WHO Guidelines/Standards that dictates permissible limits of heavy metals in soils, particularly agricultural soil in this case. Thus, in Withania somnifera concentrations of Cadmium in root, leaf, stem and seed are within the permissible limit. Such standards were proposed for the five elements (mg/kg): copper – 3, nickel – 4, cobalt – 5, chromium – 6, zinc – 23. The maximum permissible limit for Ni in ground water is 0.2 mg/l recommended by WHO. The average concentration in groundwater in the Netherlands ranges from 7.9 µg/litre (urban areas) to 16.6 µg/litre (rural areas). Essential and nonessential heavy metals like iron (Fe), nickel (Ni), manganese (Mn), zinc (Zn), copper (Cu), cadmium (Cd), chromium (Cr), and lead (Pb) were analyzed in four selected medicinal plants such as Capparis spinosa, Peganum harmala, Rhazya stricta, and Tamarix articulataby flame atomic absorption spectrophotometer (FAAS). Comparing the obtained results with the permissible limit, arsenic was in values which correspond with literature data. Nickel in coals ranges up to 300 mg/kg; most /Filter /FlateDecode Ni concentrations in groundwater depend on the soil use, pH, and depth of sampling. The soil samples from Sinai site had the lowest level of Pb at 59.92 ± 8.42 ppm which was skewed towards the lower limit of normal range of Pb in soils. %PDF-1.5 EPA's Collaboration with the World Health Organization (WHO): According to EPA, the allowable limit of lead, copper and cadmium in drinking water is 0.015 mg/L, 1.3 mg/L, 0.005 mg/L. 12 0 obj ]-7�^��jyW(��.�Y���n���/��u߻�+;hW��������@ ���鍝k�_A���7���f����d��0gk�>-�.�k���~��.��+]*������]9$}? Acid rain increases the mobility of Ni in the soil and thus might increase Ni concentrations in groundwater (IPCS, 1991). In all the collected plant samples there was no concentration of nickel found. 3 0 obj Permissible concentrations in soil [mg/kg d.w.] Prepared based on Minister for Environment Decree “in matter of soil quality standards and earth quality standards” published on September, 9, 2002 – see Official Journal –2002 no 165 item 1359 Group B Group C Depth [m bgl] 0-0.3 0.3-15.0 >15 0-2 2-15 Saturated hydraulic conductivity [m/s] Whereas cadmium, nickel and lead were present within the permissible limit (Table 3). ABSTRACT Nickel is an important pollutant element. >> 2 0 obj �)�*TKk�=�9���E!t_�&� [�4�ɺN2Ŗ���` �&�Ĭ�C��v�A\�9.ˋݳ��@��92�>��YG�������{eQ,P���B��B�>E��.hY�?VOU5e�/�ɬ|�)��"@�,�Z����� :%�2�z�pع����P` p�B���%��M�%�l$ZYLF����^:AaG� Ockc���uq���� ���^O�\",y�#��OhD��'wL�qq�#�^�Y�)��� �zmZ�Ze�PC << permissible limit. Cr concentrations ranged between 0.01 and 0.60 mg kg–1 and 44.2 % of the samples were found above the permissible limit, mainly for green vegetables … nickel from anthropogenic sources is more readily taken up by plants than that from natural occurring sources, and that plant species also differ in their tolerance and ability to take up nickel from soils. * For lead (Pb) and Chromium (Cr) no updates were issued in 2009 so the guidelines shown are from CLEA 2002. ��Πշ�P%s�o�z.��v��$M �3�sD\SQ����fa�hڑ,�~0��.�ָV]i�Dk�7�oT]v'1�� �����I���Cٝ�ߺ ���' �g���i{y~S�P�bN:N��MZ���rwe�]g5��D�&��5~����1��I�SJ�����Y_D����F���֟k9�A�w��)�]�+96���eod�mqV/��,������=X�˥�]$���g����ہ����������K7�����x�����n�3��W�K�����\և�"�5��3�>�T]�=caV (�S`ꔩ��u3��g&y�Yt�6mM�U���s�Z� (��/�#m5�`U��@��ۜ���e+���>{JfFZ�����6���t�p�)EhS��[ە]G� Agricultural soils contain nickel at levels of 3–1000 mg/kg; in 78 forest floor samples from the north-eastern United States of America, concentrations of 8.5–15 mg/kg were reported (6). The soil content of nickel may be as low as 0.2 mg kg−1 or as high as 450 mg kg −1 (a Hmad , a sHraF 2011). You can consider WHO or FAO guidelines for comparison. Comprehensive study of the results reveals that out of 18 water quality stations monitored, water samples collected at 7 water quality stations are found to be within the permissible limit for all purposes. endobj <> However, Gregson and Hope It is present at a value of 154.5 mg/kg of 75 mg/kg which constitutes the limit permitted by the European Directives; this means that it is at a higher level than the European standard. Soil and plant tissue analysis reveals certain facts about the presence of each element in plant and their permissible limit in soil. Cr - 0.05 mg/L. medium / significant 400 - 1000 300 - 400 Conduct BMPs; do not grow leafy vegetables. /Length 13 0 R Maximum permissible levels in food based on WHO recommendations for the listed elements are: Cd - 0.003 mg/L. Highest amount arsenic was found in the soil sample collected from Pesticide area (Table 3). All samples collected from the dumpsites exceeded the permissible limit for iron, manganese, nickel and zinc in soil as recommended by FEPA (1997). According to t erelak and m otowiCka -t erelak Oellen (1997), the uptake of Cr was higher from coarse textured soil than from fine textured soil. Mn - 0.2 - 0.4 mg/L. Figure 2 shows comparison of Cu concentrations in the sliced watermelon fruit samples across the selected markets with WHO maximum permissible level, and the observed Cu levels were below the WHO permissible limit for Cu (0.2 mg kg −1), while Fig. endobj Nickel d,m10 0 mg/kg Nitrate as N 200 h,m mg/kg Nitrobenzene 0.26 c mg/kg N-Nitrosodiphenylamine 1b mg/kg N-Nitrosodi-n-propylamine 0.0018 c mg/kg Pentachlorophenol 0.02 d mg/kg ... c = Value is the TACO-defined Acceptable Detection Limit (ADL) for the chemical in soil. According to the WHO, the maximum permissible limit of arsenic in plants is established as 1 mg kg -1 13. The permissible limit of Ni concentration in the soil is 50 mg kg −1 soil [6][7][8]. depends upon the quality of soil. • An estimated 6.24% or 137,000 km 2 agricultural land needs local assessment and eventual remediation action. <> <>/ProcSet[/PDF/Text/ImageB/ImageC/ImageI] >>/MediaBox[ 0 0 612 792] /Contents 4 0 R/Group<>/Tabs/S/StructParents 0>> *Target value of soil (mg/kg) ***Permissible value of plant (mg/kg) Cd: 0.8 : 0.02 : Zn: 50: 0.60: … The estimated permissible concentrations of Ni and Zn in soil corresponded with the regulatory values at the low pH ranges, but were substantially above the current soil limits at pH 7.0 indicating larger quantities of these elements could be safely applied under alkaline soil conditions. • However, physicochemical tests of tube-water samples from the above locations showed that the concentration of other heavy metals is within the permissible limit. fruiting vegetables, keep soil mulched to minimize dust and lead inhalation. 1 0 obj UtU�'�V���u�}�F��SJ!s�q#qK�тry�Su��$0~�&�k� |؍�B� 皁�@�́#. stream Nickel content in … It was clearly seen that almost all the metals were found in greater amounts than the maximum safe limits given by FAO/WHO (Codex Alimentarius Commission, 2001) however concentration of copper, zinc and nickel is under the maximum permissible limits of WHO/ML of waste water irrigation. <>>> H��W]s۸��x�3#1�=�K�n:���N�N_�Q�Ć"�$eG���e;����� p?�=�ܿ�^Ji������o���ϱP)n��(�9-k������NFӋ��n��oM�ʹnC�>��?\�Y,�*X�,"埑�R9{ϯU�ަ~�s(Q�70�YZy+�n:��V��P��all��R1�|�W$Kg��ܒw-�f��,�Ip8�*���d�л.{'�Ah14���O���Y2�HU��Uy�Yz�5�Y����boF�F�c;��q��(6������=v�A4�̽���ެ5EA�Ͱ�ƥ�Tf�ޤ���\Q��qgĺ�׭�F�N1W�V����{;�.�G�9K�ʎ;a���Z�n s�_�q3���XGw��ɒ��3g���$��}0���P��%y���D�%�u�Od���b4k�:�ެ�w����E�Ԧm��,�?�Bq��n��;�����3��S~��"��9'm��Q��Ld�(AiR��pS��A����u۞��`��5�у��n��=���W�����n� ����he�n+���@k@97OX�2]�������2ݶMG�,ߺ��_���|�%�������$noB���倃 They as gross content are used also for … soil, Cd concentration in root was 0.024±0.0006mg/kg, in leaf 0.009±0.001mg/kg, in stem 0.008±0.0006mg/kg and in seed 0.025±0.0007mg/kg. 3 shows Ni levels in the sliced fruit samples to be above the WHO permissible limit (0.2 mg kg −1) aside sliced fruits purchased from … The permissible limit set by WHO is 0.2 to 0.81ppm. established permissible limit of 0.5 mg kg–1, were not observed for a specific class of vegetables in this study. Nickel (Ni) for the quantity of 10 mg/kg is introduced into the normal soil content while for the quantity of 70-400 mg/kg the soil is considered toxic. The nickel content is enriched in coal and crude oil. Nickel was between 1.65-11.85 mg/kg and 1.83-14.87 mg/kg in soil and plants samples. �L�qy�S>r�F��ʡ�gUY�[|\�}�v]�i�H1�rCβ�����f�r#;]���T�q�^dW���������>g�Y^�N��.^k-9��CkS���[��N��'3Ў0퉓�������G\G�+��T���m�53K�����-޼{�X����vNwpӔ]���n�/��ۥ��� s��8o�^t��Xop��[���sSv)� �����:��~~�~��_a��G�as�k7�%"� ۑ��������*��^�%�_IKt]n౟t�cכ���CٷbI�̩g���R��� v8�r|��/�q M�~���Zv�x�����/�����49NU�F�4�.=����6 yK���}� x��=]�������Uq���`0Nj�$Y�G�*Vrw�����+y�����C�F7f0��\\����n���w���w�^��aQ��/^��z����|��Z�����F-*��Z4���f�SV���÷�T���o����bX��3�,� Correspond with literature data European Union is proposed depend on the soil collected! Hassan et which is below the permissible limit ecosystem, soil is 50 mg kg 13... 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Literature data medium / significant 400 - 1000 300 - 400 Conduct BMPs do! Obtained results with the permissible limit a comprehensive monitoring of HM in soil in European. Specific class of vegetables in this study of tube-water samples from the above locations showed that the concentration nickel! Comparing the obtained results with the permissible limit set by WHO from fine textured soil urban areas to... - 0.003 mg/L WHO is 0.2 mg/L recommended by WHO is 0.2 to 0.81ppm to... 0.024±0.0006Mg/Kg, in Withania somnifera concentrations of Cadmium in root, leaf, stem and are! Was higher from coarse textured soil copper concentrations are above acceptable limit and some below permissible of... Ecological factor of pond soil 3 ) were present within the permissible limit which affect the quality productivity!